137105-43-2

Basic information

• Product Name: N-(4-(hydroxymethyl)phenyl)pivalamide
• Synonyms: N-(4-(hydroxymethyl)phenyl)pivalamide
• CAS NO: 137105-43-2
• Molecular Weight: 207.272
• Mol File: 137105-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-(hydroxymethyl)phenyl)pivalamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-(hydroxymethyl)phenyl)pivalamide(137105-43-2)
• EPA Substance Registry System: N-(4-(hydroxymethyl)phenyl)pivalamide(137105-43-2)

Safety Data

• Hazardous Substances Data: 137105-43-2(Hazardous Substances Data)

Upstream product

• 623-04-1 4-aminobenzenemethanol 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 1150560-88-5 2,2-dimethyl-N-[4-(2-oxo-2,3-dihydro-1H-indol-3-ylmethyl)-phenyl]-propionamide 
• 1533458-01-3 4-pivalamidobenzyl 2-methoxyacetate 
• 898124-76-0 2-(4-pivalamidophenyl)acetic acid 
• 137105-35-2 N-(4-{(2R,3R,4R,5S,6R)-3-Acetylamino-2-allyloxy-5-benzyloxy-6-[4-(2,2-dimethyl-propionylamino)-benzyloxymethyl]-tetrahydro-pyran-4-yloxymethyl}-phenyl)-2,2-dimethyl-propionamide 
• 137105-34-1 N-[4-((2R,3S,4R,5R,6R)-5-Acetylamino-4,6-bis-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yloxymethyl)-phenyl]-2,2-dimethyl-propionamide 
• 137105-33-0 N-[4-((2R,4aR,6R,7R,8S,8aR)-6-Allyloxy-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxymethyl)-phenyl]-2,2-dimethyl-propionamide 
• 137105-32-9 N-{4-[(3aR,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxymethyl]-phenyl}-2,2-dimethyl-propionamide 
• 137105-31-8 Benzoic acid (S)-2-benzyloxy-3-[4-(2,2-dimethyl-propionylamino)-benzyloxy]-propyl ester 
• 137105-30-7 N-{4-[2-(4-Methoxy-benzyloxy)-ethoxymethyl]-phenyl}-2,2-dimethyl-propionamide 
• 137105-37-4 4-pivaloylaminobenzyl bromide 
• 137105-36-3 4-pivaloylaminobenzyl chloride 
• 137105-38-5 p-pivalolaminobenzyl 2,2,2-trichloroacetimidate 

Relevant articles and documents

4-Pivaloylaminobenzyl ether, a new temporary protection for hydroxyl functions

4-Pivaloylaminobenzyl (PAB) group is a new benzyl-type protecting group which can be introduced either by initial introduction of 4-nitrobenzyl group followed by reduction and N-acylation or by the reaction of a hydroxyl compound with the corresponding halogenide or trichloroacetimidate. PAB ethers have higher acid stability than 4-methoxybenzyl ethers but are readily cleaved with DDQ in a manner similar to the latter.