137152-59-1

Upstream product

• 64-17-5 ethanol 
• 102862-46-4 3-p-Tolyl-oxirane-2,2-dicarbonitrile 
• 108-98-5 thiophenol 
• 14062-19-2 p-tolylacetic acid ethyl ester 
• 882-33-7 diphenyldisulfane 
• 106372-59-2 ethyl 2-fluoro-2-(phenylsulfanyl)acetate 
• 108-88-3 toluene 

Relevant academic research and scientific papers

First Lewis acid catalyzed generation and reaction of α- organylsulfanyl and α-organylselanyl carbenium ions using ethyl α-fluoroacetate derivatives

Lewis acid catalyzed generation and reactions of α-organylsulfanyl and α-organylselanyl carbenium ions with nucleophiles proceeded in high yields using α-fluoro-α-organylsulfanyl- and α-fluoro-α- organylselanylacetate and 5 mol-% scandium triflate. Wiley-

PTC sulfanylation of arylacetates

Phase-transfer catalysis, in the absence of solvent, was successfully applied to the sulfanylation of a series of arylacetates leading, in most cases, to acceptable yields of α-monosulfanylated derivatives.

A facile one-pot synthesis of α-hydroxy acids and their derivatives

2-Substituted oxirane-1,1-dicarbonitriles react with water, alcohols or phenol to give 2-substituted 2-hydroxyacetic acids, alkyl-2-alkoxyacetates and phenyl 2-phenoxyacetates, respectively. Reaction of 2-substituted oxirane-1,1-dicarbonitrile with thiophenol and a nucleophile, typically water ethanol or urea, gave 2-(phenylthio)acetic acids, ethyl 2-(phenylthio)acetates and N-aminocarbonyl-2-(phenylthio)acetamides.