13719-81-8

Basic information

• Product Name: 3,4,5,6-Tetrafluoro-o-xylene-alpha,alpha'-diol
• Synonyms: 3,4,5,6-Tetrafluoro-1,2-benzenedimethanol;3,4,5,6-Tetrafluoro-o-xylene-alpha,alpha'-diol
• CAS NO: 13719-81-8
• Molecular Formula: C₈H₆F₄O₂
• Molecular Weight: 210.13
• Mol File: 13719-81-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 261℃
• Flash Point: 112℃
• Appearance: /
• Density: 1.569
• CAS DataBase Reference: 3,4,5,6-Tetrafluoro-o-xylene-alpha,alpha'-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5,6-Tetrafluoro-o-xylene-alpha,alpha'-diol(13719-81-8)
• EPA Substance Registry System: 3,4,5,6-Tetrafluoro-o-xylene-alpha,alpha'-diol(13719-81-8)

Safety Data

• Hazardous Substances Data: 13719-81-8(Hazardous Substances Data)

Upstream product

• 652-03-9 3,4,5,6-tetrafluorophthalic acid 
• 652-12-0 4,5,6,7-tetrafluoroisobenzofuran-1,3-dione 
• 13719-80-7 diethyl 3,4,5,6-tetrafluorophthalate 

Downstream Products

• 1402159-56-1 C₄₉H₄₅NO₉ 
• 13719-82-9 1,2-bis-bromomethyl-3,4,5,6-tetrahydrofluorobenzene 
• 859849-47-1 5,6,7,8-tetrafluoroanthracene-1,4-dione 

Relevant articles and documents

A Unified Catalytic Asymmetric (4+1) and (5+1) Annulation Strategy to Access Chiral Spirooxindole-Fused Oxacycles

A unified catalytic asymmetric (N+1) (N=4, 5) annulation reaction of oxindoles with bifunctional peroxides has been achieved in the presence of a chiral phase-transfer catalyst (PTC). This general strategy utilizes peroxides as unique bielectrophilic four- or five-atom synthons to participate in the C?C and the subsequent umpolung C?O bond-forming reactions with one-carbon unit nucleophiles, thus providing a distinct method to access the valuable chiral spirooxindole-tetrahydrofurans and -tetrahydropyrans with good yields and high enantioselectivities under mild conditions. DFT calculations were performed to rationalize the origin of high enantioselectivity. The gram-scale syntheses and synthetic utility of the resultant products were also demonstrated.

Functionalized and Degradable Polyphthalaldehyde Derivatives

Polymers that depolymerize back to monomers can be repeatedly chemically recycled, thereby reducing their environmental impact. Polyphthalaldehyde is a metastable polymer that can rapidly and quantitatively depolymerize due to its low ceiling temperature. However, the effect of substitution on the physical and chemical properties of polyphthalaldehyde derivatives has not been systematically studied. Herein, we investigate the cationic polymerization of seven o-phthalaldehyde derivatives and demonstrate that judicious choice of substituent results in materials with a wide range of ceiling temperatures (-60 to 106 °C) and decomposition temperatures (109-196 °C). We anticipate that these new polymers and their derivatives will enable researchers to access degradable materials with tunable thermal, physical, and chemical properties.

Phenoxybenzyl 2-[2-(2-hydroxy)indanyl]-3-methyl-butanoates

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