137233-96-6Relevant academic research and scientific papers
Cyclization Reactions of Rhodium Carbene Complexes. Effect of Composition and Oxidation State of the Metal
Padwa, Albert,Kassir, Jamal M.,Xu, Simon L.
, p. 1642 - 1652 (2007/10/03)
Treatment of o-(1,7-octadiynyl)benzoyldiazoethane with rhodium(II) octanoate in pentane resulted in a double internal/internal alkyne insertion reaction producing a labile bicyclo[4.1.0]hept-1(7)-ene derivative which readily undergoes a Diels-Alder reacti
Rhodium-Catalyzed Ring-Opening Reaction of Cyclopropenes. Control of Regioselectivity by the Oxidation State of the Metal
Padwa, Albert,Kassir, Jamal M.,Xu, Simon L.
, p. 6971 - 6972 (2007/10/02)
The Rh(II)-catalyzed reaction of unsymmetrically substituted cyclopropenes gives substituted furans derived from cleavage of the less substituted α-bond.In contrast, Rh(I) catalysis results in cleavage of the more substituted α-bond producing a regioisome
