14088-57-4

Basic information

• Product Name: (1Z)-2-diazonio-1-phenylprop-1-en-1-olate
• CAS NO: 14088-57-4
• Molecular Formula: C₉H₈N₂O
• Molecular Weight: 160.1726
• Mol File: 14088-57-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (1Z)-2-diazonio-1-phenylprop-1-en-1-olate(CAS DataBase Reference)
• NIST Chemistry Reference: (1Z)-2-diazonio-1-phenylprop-1-en-1-olate(14088-57-4)
• EPA Substance Registry System: (1Z)-2-diazonio-1-phenylprop-1-en-1-olate(14088-57-4)

Safety Data

• Hazardous Substances Data: 14088-57-4(Hazardous Substances Data)

Upstream product

• 1117-96-0 Diazoethan 
• 98-88-4 benzoyl chloride 
• 93-55-0 1-phenyl-propan-1-one 
• 624-90-8 Methanesulfonyl azide 
• 35947-99-0 2-azido-1-phenyl-1-propanone 
• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 579-07-7 1-Phenylpropane-1,2-dione 
• 322-06-5 4,4,4-trifluoro-2-methyl-1-phenyl-1,3-butanedione 
• 3516-69-6 3-hydroxy-2-methyl-1-phenyl-2-propen-1-one 
• 16837-43-7 2-benzoylpropanal 

Downstream Products

• 6493-83-0 2-methoxy-1-phenyl-propan-1-one 
• 768-03-6 Phenyl vinyl ketone 
• 113859-95-3 1,2,4-Trimethyl-5-phenyl-1H-pyrrole-3-carboxylic acid ethyl ester 
• 92-52-4 biphenyl 
• 492-37-5 hydratropic acid 
• 98-86-2 acetophenone 
• 93-55-0 1-phenyl-propan-1-one 
• 134-81-6 benzil 
• 410522-20-2 3-acetyl-1-phenyl-1-methyl-4-(methylamino)-3-penten-2-one 
• 4452-11-3 1,2-diphenylprop-2-en-1-one 
• 2042-85-5 1,2-diphenylpropan-1-one 
• 32142-34-0 1-phenyl-2-(phenylamino)propane-1-one 
• 1612226-18-2 1-phenyl-2-[(trifluoromethyl)sulfanyl]propan-1-one 
• 90484-46-1 2-bromo-1-phenylprop-2-en-1-one 

Relevant articles and documents

Practical Application of the Aqueous 'Sulfonyl-Azide-Free' (SAFE) Diazo Transfer Protocol to Less α-C-H Acidic Ketones and Esters

The earlier described 'sulfonyl-Azide-free' ('SAFE') protocol for diazo transfer to CH-Acidic 1,3-dicarbonyl compounds (and their similarly activated congeners) has been extended to the less reactive monocarbonyl substrates, which previously required a se

Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes

Supported Au nanoparticles on TiO2 catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes. It is proposed that the transformation involves two modes of catalytic activation: formation of nucleophilic Au carbenes on the surface of nanoparticle via expulsion of N2 and activation of the Si-H bond of hydrosilane on Au nanoparticle, followed by coupling of the chemisorbed species. No external ligands or additives are required, while the process is purely heterogeneous, thus allowing the recycling and reuse of the catalyst.

Cyclization Reactions of Rhodium Carbene Complexes. Effect of Composition and Oxidation State of the Metal

Treatment of o-(1,7-octadiynyl)benzoyldiazoethane with rhodium(II) octanoate in pentane resulted in a double internal/internal alkyne insertion reaction producing a labile bicyclo[4.1.0]hept-1(7)-ene derivative which readily undergoes a Diels-Alder reacti