1372559-65-3Relevant academic research and scientific papers
Nickel-catalyzed C-P coupling of aryl mesylates and tosylates with H(O)PR1R2
Shen, Chaoren,Yang, Guoqiang,Zhang, Wanbin
, p. 3500 - 3505 (2012)
A method was developed for the nickel-catalyzed phosphonylation of aryl mesylates and tosylates with H(O)PR1R2. To the best of our knowledge, this is the first example of nickel-catalyzed C-P coupling of aryl mesylates and tosylates. Most of the substrates gave moderate to good yields under our catalytic system.
General Oxidative Aryl C-P Bond Formation through Palladium-Catalyzed Decarbonylative Coupling of Aroylhydrazides with P(O)H Compounds
Dong, Jianyu,Liu, Long,Ji, Xuyu,Shang, Qian,Liu, Lixin,Su, Lebin,Chen, Bing,Kan, Ruifeng,Zhou, Yongbo,Yin, Shuang-Feng,Han, Li-Biao
supporting information, p. 3198 - 3203 (2019/05/10)
Oxidative C-C/P-H cross-coupling is achieved via Pd-catalyzed decarbonylative cross-coupling of aroylhydrazides with P(O)H compounds. The unique cooperative reaction system, especially the Br?nsted acid and bidentate phosphine ligand, allows the selective activation of the inert C-C bond and the suppression of the undesired oxidation and coordination of >P(O)-H compounds, leading to a general oxidative synthesis of aryl phosphorus compounds from easily available substrates.
