137334-99-7Relevant academic research and scientific papers
Heavy silylchalcogenido lanthanates synthesis Ph4P[Cp3La-ESiMe3] (E = S, Se, and Te): Via fluoride-induced demethylation of dimethylcarbonate to Ph4P[OCO2Me] key intermediate
Guschlbauer, Jannick,Vollgraff, Tobias,Xie, Xiulan,Fetoh, Ahmed,Sundermeyer, J?rg
supporting information, p. 13103 - 13111 (2021/10/12)
We report a new high-yield synthesis of so far not accessible tetraphenylphosphonium methylcarbonate Ph4P[OCO2Me] via solvothermal fluoride-induced demethylation and MeF elimination at Me2CO3 (DMC) by Ph4P-F, structurally characterized as λ5-fluorophospho
Anhydrous phosphazenium fluorides as sources for extremely reactive fluoride ions in solution
Schwesinger, Reinhard,Link, Reinhard,Wenzl, Peter,Kossek, Sebastian
, p. 438 - 445 (2008/09/19)
Several peralkylated polyaminophosphazenium cations were evaluated for the generation of novel anhydrous F- salts. Two of them have been characterized by X-ray analysis and are particularly soluble, even in apolar aprotic solvents like benzene
