1373395-20-0Relevant academic research and scientific papers
Total synthesis of 7′-desmethylkealiiquinone, 4′- desmethoxykealiiquinone, and 2-deoxykealiiquinone
Lima, Heather M.,Sivappa, Rasapalli,Yousufuddin, Muhammed,Lovely, Carl J.
, p. 2481 - 2490 (2014/04/17)
Synthetic approaches to the imidazonaphthoquinone core of kealiiquinone and related Leucetta-derived alkaloids are described. The polysubstituted benzimidazole framework can be constructed through intramolecular Diels-Alder reactions of propiolate-derived
Total synthesis of 7′-desmethylkealiiquinone
Lima, Heather M.,Sivappa, Rasapalli,Yousufuddin, Muhammed,Lovely, Carl J.
, p. 2274 - 2277 (2012/06/30)
The total synthesis of an analogue of the marine alkaloid kealiiquinone has been completed through application of an intramolecular Diels-Alder reaction of an imidazole-containing enyne. Oxidative aromatization of the lactone adduct and N-methylation faci
