137369-57-4Relevant academic research and scientific papers
Lewis acid-mediated azidolysis of 2,3-three membered heterocyclic amines
Righi, Giuliana,Scotti, Giorgio,Caruso, Francesco,Rossi, Miriam,Mecozzi, Francesco,Antonioletti, Roberto,Pelagalli, Romina
, p. 9557 - 9565 (2013)
The Lewis acid-catalyzed regioselective azidolysis of 2,3-three membered heterocyclic amines has been investigated. The results obtained demonstrated that using TMSN3 as a source of azide, the appropriate choice of Lewis acid allowed to obtain
MgBr2-mediated opening of 2,3-three membered heterocyclic amines
Righi, Giuliana,Ciambrone, Simona,Esuperanzi, Evelina,Montini, Francesca,Pelagalli, Romina
scheme or table, p. 564 - 568 (2010/09/05)
(Chemical Equation Presented) Regio- and stereo-controlled opening of 2,3-epoxy amines and 2,3-aziridine amines by the commercially available MgBr2 is described. As reported, this new method could represent a general and useful approach for the preparation of promising intermediates. Moreover, in particular cases, the reaction evolves toward an interesting oxazolidin-2-one structure.
