137428-93-4

Basic information

• Product Name: 1,2-diphenylpropan-1-amine(anti-3ak)and
• CAS NO: 137428-93-4
• Molecular Weight: 211.307
• Mol File: 137428-93-4.mol

Chemical Properties

• CAS DataBase Reference: 1,2-diphenylpropan-1-amine(anti-3ak)and(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-diphenylpropan-1-amine(anti-3ak)and(137428-93-4)
• EPA Substance Registry System: 1,2-diphenylpropan-1-amine(anti-3ak)and(137428-93-4)

Safety Data

• Hazardous Substances Data: 137428-93-4(Hazardous Substances Data)

Upstream product

• 41997-47-1 1,1-diphenyl-2-propanol 
• 6941-83-9 1,2-diphenyl-propan-1-one oxime 
• 2042-85-5 1,2-diphenylpropan-1-one 
• 28795-94-0 1,2-diphenyl-1-propanol 
• 100-41-4 ethylbenzene 
• 100-52-7 benzaldehyde 
• 781-35-1 1,1-diphenylacetone 
• 540-69-2 ammonium formate 

Downstream Products

• 95430-90-3 ((1RS,2SR)-1,2-diphenyl-propyl)-dimethyl-amine 

Relevant articles and documents

Catalytic Direct-Type Addition Reactions of Alkylarenes with Imines and Alkenes

Catalytic addition reactions of very weakly acidic nonactivated alkylarenes such as toluene and its derivatives were developed by using a strongly basic mixed catalyst system under mild reaction conditions. The addition reactions with imines and alkenes proceeded smoothly under proton-transfer conditions to afford the desired products in good to high yields, and high levels of regio- and stereoselectivity were achieved. It was also revealed that the asymmetric addition reaction of an alkylarene was possible.

Alkaline-metal-catalyzed one-pot aminobenzylation of aldehydes with toluenes

A novel and easily accessible MN(SiMe3)2 (M = Li or Na)/Cs2CO3 co-catalyzed benzylation of in situ generated N-(trimethylsilyl) aldimines with toluene derivatives has been successfully developed. The catalyst exhibits high chemoselectivity for deprotonation of toluenes at the benzylic position. The utility of this system is exemplified by the one-pot synthesis of a diverse array of bioactive 1,2-diarylethylamines with excellent efficiency and broad functional group tolerance.