137436-45-4Relevant academic research and scientific papers
Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis-Hydride-η2-Dihydrogen Complexes [{P(CH2CH2PPh2)3}M (H)(η2-H2)]+ (M = Fe, Ru)
Bianchini, Claudio,Masi, Dante,Peruzzini, Maurizio,Casarin, Maurizio,Maccato, Chiara,Rizzi, Gian Andrea
, p. 1061 - 1069 (2008/10/09)
Ab initio calculations (DMOL method) including the estimate of the total energy and the full optimization of the geometrical parameters have been used to study the electronic structures and the coordination geometries of the model systems [{P(CH2CH2PH2)3}M (H) (L)]+ (M = Fe, L = H2, C2H4, CO, N2; M = Ru, L = H2). Single crystal X-ray analyses have been carried out on the complexes [(PP3)Fe (H)(η2-H2)]BPh4·0.5THF (1·0.5THF), [(PP3)Fe (H)(CO)]BPh4·THF(3·THF), and [(PP3)Ru (H)(η2-H2)]BPh 4·0.5THF(5·0.5THF) [PP3 = P(CH2CH2PPh2)3]. Crystal data: for 1·0.5THF, triclinic P1 (No. 2), a = 17.626(3) A?, b = 14.605(3) A?, c = 12.824(4) A?, α = 90.09(2)°, β = 103.87(2)°, γ = 107.46(2)°, Z = 2, R = 0.082; for 3·THF, triclinic P1 (No. 2), a = 12.717(2) A?, b = 14.553(1) A?, c = 17.816(2) A?, α = 72.90(1)°, β = 76.82(2)°, γ = 89.71(1)°, Z = 2, R = 0.067; for 5·0.5THF, monoclinic P2/1a (No. 14), a = 19.490(5) A?, b = 19.438(2) A?, c = 16.873(5) A?, β= 110.96(2)°, Z = 4, R = 0.074. On the basis of theoretical calculations, X-ray analyses, and multinuclear NMR studies, all of the complexes of the formula [(PP3)M (H) (L)]BPh4 [M = Fe, L = H2 (1), C2H4 (2), CO (3), N2 (4); M = Ru, L = H2 (5), C2H4 (6)] are assigned a distorted octahedral structure where the hydride (trans to a terminal phosphorus donor) and the L ligand occupy mutually cis positions. The theoretical calculations indicate that the H2 ligand in the η2-dihydrogen-hydride derivatives 1 and 5 is placed in the P-M-H plane (parallel orientation) and that there is an attractive interaction between the H and H2 ligands. XPS measurements, performed on the iron complexes, show that the Fe → L back-bonding interaction plays a leading role in 3. It is concluded that the stronger metal-H2 bond in the dihydrogen-hydride complex 1, as compared to the Ru analog 5, is due to the greater d(metal) → σ*(H-H) back-donation as well as a more efficient interaction between the terminal hydride and an H of the dihydrogen ligand. This cis effect is suggested to contribute to the relative stability of the iron complexes, which increases in the order C2H4 2 2 CO.
Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride η2-dihydrogen complex. A case of intramolecular reaction between η2-H2 and σ-vinyl ligands
Bianchini, Claudio,Meli, Andrea,Peruzzini, Maurizio,Frediani, Piero,Bohanna, Cristina,Esteruelas, Miguel A.,Oro, Luis A.
, p. 138 - 145 (2008/10/08)
The reactions of the cis-hydride η2-dihydrogen complex [(PP3)Fe(H)(H2)IBPh4 (1) and of the dinitrogen derivative [(PP3)Fe(H)(N2)]BPh4 (2) with a variety of 1-alkynes have been investigated. From this study, it is apparent that the insertion of the alkyne across the Fe-H bond in 1 to give a σ-alkenyl intermediate proceeds via decoordination of a phosphine arm of PP3 rather than via H2 decoordination. Terminal alkynes are selectively and catalytically hydrogenated to alkenes by 1 in tetrahydrofuran or 1,2-dichloroethane solutions under mild conditions. A kinetic study on the hydrogenation reaction of HC≡CPh to H2O=CHPh has shown that the reduction is first order in catalyst and alkyne concentrations and zero order in hydrogen pressure. Incorporation of a large body of experimental data leads to the conclusion that (i) the dihydrogen ligand does not leave the metal prior to alkyne coordination and (ii) the reduction of the substrate most likely occurs via an intramolecular acid/base reaction involving η2-H2 and σ-vinyl ligands mutually cis disposed.
