137438-47-2Relevant articles and documents
Silicomolybdic acid supported on silica gel: An efficient catalyst for Hosomi-Sakurai reactions
Murugan, Kaliyappan,Srimurugan, Sankareswaran,Chen, Chinpiao
experimental part, p. 5621 - 5629 (2011/08/09)
Silicomolybdic acid that is supported on silica gel (50 wt %) efficiently catalyzes the high-yielding Hosomi-Sakurai allylation of carbonyl compounds by allyltrimethylsilane in the presence of benzyl alcohol. The reaction rates of inactive substrates and the yields were greatly increased when preformed acetals were used as substrates.
Iron(III) chloride-catalyzed convenient one-pot synthesis of homoallyl benzyl ethers starting from aldehydes
Watahiki, Tsutomu,Akabane, Yusuke,Mori, Seiji,Oriyama, Takeshi
, p. 3045 - 3048 (2007/10/03)
(Matrix presented) Iron(III) chloride-catalyzed effective allylation reactions of acetals with allyltrimethylsilane proceeded smoothly in high to excellent yields. In addition, this method could be applied to the one-pot synthesis of homoallyl benzyl ethe
Novel reactions of ethylene acetals with silyl-substituted nucleophiles. A mild and efficient procedure for the synthesis of homoallyl alkyl ethers and unsymmetrical dialkyl ethers
Suzuki, Takeshi,Oriyama, Takeshi
, p. 1263 - 1269 (2007/10/03)
Efficient one-pot synthesis of homoallyl alkyl ethers and dialkyl ethers was performed by the allylation and reduction of ethylene acetals with allyltrimethylsilane and t-butyldimethylsilane, respectively, in the presence of alkoxytrimethylsilane.
