13749-55-8

Upstream product

• 74-90-8 hydrogen cyanide 
• 111-92-2 dibutylamine 
• 29392-46-9 ethyl thioformate 
• 761-65-9 N,N-dibutylformamide 
• 2944-05-0 carbon monosulfide 
• 419532-33-5 N-phenyl-1,2,3,4,5,7-pentathioazocane 

Downstream Products

• 59408-53-6 N,N-dibutyl-2,2-diphenyl-2-hydroxy-thioacetamide 
• 59408-48-9 2,2-dicyclohexyl-2-hydroxy-N,N-dibutylthioacetamide 
• 59408-47-8 2-hydroxy-2-phenyl-N,N-dibutylthioacetamide 

Relevant academic research and scientific papers

Novel thiofomylation of primary and secondary amines using N-aryl-1,2,3,4,5,7-pentathiazocanes

Heating of N-aryl-1,2,3,4,5,7-pentathiazocanes 1 in the presence of primary and secondary amines afforded N-Alkyl or N,N-dialkylthioformamides 5, and similar heating of 1 in the absence of amines afforded an inseparable mixture of acyclic polysulfides 4 bearing a thioformanilide moiety on each terminal. Bisthioformanilides 4 were also converted into 5 by treating with these amines, and the thioformylation was assumed to proceed through a pathway involving the ring fission of 1 and the subsequent nucleophilic attack of these amines onto the thioformyl group of 4. Copyright Taylor & Francis Group.