137567-79-4

Basic information

• Product Name: 5-Cyclohexene-1,2,3,4-tetrol, (1R,2R,3R,4R)-
• CAS NO: 137567-79-4
• Molecular Formula: C6H10O4
• Molecular Weight: 146.143
• Mol File: 137567-79-4.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: 5-Cyclohexene-1,2,3,4-tetrol, (1R,2R,3R,4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Cyclohexene-1,2,3,4-tetrol, (1R,2R,3R,4R)-(137567-79-4)
• EPA Substance Registry System: 5-Cyclohexene-1,2,3,4-tetrol, (1R,2R,3R,4R)-(137567-79-4)

Safety Data

• Hazardous Substances Data: 137567-79-4(Hazardous Substances Data)

Upstream product

• 438035-36-0 (-)-(1R,2S,3S,4R)-1,4-di-O-benzoyl-2,3-O-isopropylidenecyclohex-5-ene-1,2,3,4-tetrol 
• 371155-83-8 (3aS,4S,7R,7aS)-3a,4,7,7a-tetrahydro-2,2-dimethyl-1,3-benzodioxole-4,7-diol dibenzoate 
• 535994-37-7 (2S,3R)-2,3-dibenzyloxy-4-penten-1-al 
• 538334-70-2 (1R,2S,5R,6R)-5,6-dibenzyloxy-2-(dimethylphenylsilanyl)cyclohex-3-enol 
• 538334-67-7 (3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)octa-1,7-dien-4-ol 
• 538334-65-5 (1S,2S,3S,4R,5S,6R)-5,6-dibenzyloxy-3-(dimethylphenylsilanyl)cyclohexane-1,2,4-triol 
• 371155-64-5 (3aS,4R,7R,7aS)-3a,4,7,7a-tetrahydro-2,2-dimethyl-1,3-benzodioxole-4,7-diol 
• 371155-82-7 (3aS,4R,7R,7aS)-3a,4,7,7a-tetrahydro-2,2-dimethyl-1,3-benzodioxole-4,7-diol 4-monobenzoate 
• 17793-95-2 cis-1,2-dihydrocatechol 
• 55990-85-7 (1S,2R,5S,6R)-7-Oxa-bicyclo[4.1.0]hept-3-ene-2,5-diol 
• 4381-96-8 (+/-)-tetraacetylconduritol C 
• 5273-61-0 (5RS,6RS)-5,6-dibromocyclohex-2-ene-1,4-dione 
• 69945-44-4 (1RS,2SR,3RS,4RS)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 106-51-4 p-benzoquinone 

Downstream Products

• 347377-78-0 C₂₉H₂₄F₃NO₉S 
• 347377-82-6 C₂₉H₂₅NO₈ 
• 347377-80-4 C₂₈H₂₅NO₈ 
• 347377-76-8 (+)-(1S,2R,3R,4S)-1,4-Dibenzoyloxy-2-(N-benzyl)carbamyl-5-cyclohexene-3-ol 
• 347377-79-1 C₂₈H₂₃NO₆ 
• 253584-54-2 (+)-(1S,2R,3R,4S)-1,4-Dibenzoyloxy-2,3-di[(2,2,2-trichloroethoxy)carbonyl]oxy-5-cyclohexene 
• 347377-81-5 (+)-(1S,2R,3R,4S)-1,4-Dibenzoyloxy-5-cyclohexene-2,3-diol 
• 852045-24-0 (1S,2R,3S,4R,5R,6S)-N-(2,3,4,5,6-pentakis-benzyloxycyclohexyl)octanamide 

Relevant articles and documents

Toluene dioxygenase-mediated oxidation of dibromobenzenes. Absolute stereochemistry of new metabolites and synthesis of (-)-conduritol E

Dibromobenzenes (o-, m-, and p-isomers) were converted to the corresponding cis-cyclohexadiene diols by whole-cell fermentation with Escherichia coli JM 109 (pDTG601A), an organism over-expressing the enzyme toluene dioxygenase (TDO). Absolute stereochemi

Directed dihydroxylation of cyclic allylic alcohols and trichloroacetamides using OsO4/TMEDA

The oxidation of a range of cyclic allylic alcohols and amides with OsO4/TMEDA is presented. Under these conditions, hydrogen bonding control leads to the (contrasteric) formation of the syn isomer in almost every example that was examined. Evidence for the bidentate binding of TMEDA to OsO4 is presented and a plausible mechanism described.