137654-28-5Relevant academic research and scientific papers
Organocatalytic enantioselective Michael addition of α-nitroacetate to α,β-unsaturated enones: A route to chiral γ-nitro ketones and δ-keto esters
Moon, Hyoung Wook,Kim, Dae Young
experimental part, p. 291 - 295 (2011/11/12)
The catalytic enantioselective conjugate addition reaction of α-nitroacetate to α,β-unsaturated enones promoted by chiral bifunctional organocatalysts is described. The treatment of α-nitroacetate to α,β-unsaturated enones afforded the corresponding Micha
A general organocatalytic enantioselective malonate addition to α,β-unsaturated enones
Wascholowski, Veit,Knudsen, Kristian Rahbek,Mitchell, Claire E. T.,Ley, Steven V.
experimental part, p. 6155 - 6165 (2009/05/27)
A general enantioselective organocatalytic conjugate addition procedure of a variety of malonates to α,β-unsaturated enone systems is presented. The reaction is efficiently catalysed by the pyrrolidinyl tetrazole catalyst 1. Cyclic, acyclic and aromatic e
