1376608-47-7Relevant academic research and scientific papers
Synthesis of polyfluorinated aromatic ethers and thioethers by synergistic cleavage of C-B bond and C-F bond of B(C6F5)3
Ma, Cui-Cui,Zhu, Xing-Xing,Liu, Li,Dai, Jian-Jun,Xu, Jun,Xu, Hua-Jian
supporting information, (2021/09/11)
A concise and efficient method for the synthesis of polyfluorinated aromatic ethers and thioethers by synergistic cleavage of C-B bond and C-F bond of B(C6F5)3 is reported. The reaction could proceed smoothly with excellent functional-group compatibility. In addition, the transformation represents the first general application of B(C6F5)3 as reaction partners in cross-coupling reaction.
2-ARYLSULFONAMIDO-N-ARYLACETAMIDE DERIVATIZED STAT3 INHIBITORS
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Paragraph 00936; 00938, (2018/08/20)
The present disclosure provides pharmaceutical compositions comprising 2-arylsulfonamido-N-arylacetamide derivatized Stat3 inhibitors and certain pharmaceutically acceptable salts thereof, and methods of their use.
Regioselective C-S bond formation accomplished by copper-catalyzed regioselective C-F substitution of perfluoroarenes with aryl thioacetates or benzyl thioacetate
Zhou, Qizhong,Zhang, Bin,Du, Tieqi,Gu, Haining,Jiang, Huajiang,Chen, Rener
experimental part, p. 4233 - 4241 (2012/07/14)
Practical and straightforward method for regioselective C-S bond formation accomplished by copper-catalyzed regioselective C-F substitution of electron-deficient perfluoroarenes with aryl thioacetates or benzyl thioacetate has been developed. Because of its high reaction efficiency, good chemoselectivity and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to polyfluoroaryl thioethers used for drugs and material chemistry.
