137694-05-4

Upstream product

• 67-56-1 methanol 
• 75-52-5 nitromethane 
• 124-41-4 sodium methylate 
• 10019-70-2 7-ethoxy-9-hydroxy-6-α-methoxy-2-phenyl-trans-(1,3-dioxano)<5,4-e><1:4>-dioxepan 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 111065-10-2 (4aR)-7ξ-Acetoxy-6c,9ξ-dimethoxy-2c-phenyl-(4ar,9at)-hexahydro-[1,3]dioxino[5,4-e][1,4]dioxepin 
• 123936-12-9 (4aR)-6c,7ξ-Dimethoxy-9ξ-(4-nitro-benzoyloxy)-2c-phenyl-(4ar,9at)-hexahydro-[1,3]dioxino[5,4-e][1,4]dioxepin 
• 137616-52-5 (E)-4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-but-3-en-2-one 
• 137616-51-4 (2R,4S,5R)-5-((E)-(S)-1-Methoxy-3-phenyl-allyloxy)-2-phenyl-4-((E)-styryl)-[1,3]dioxane 
• 115997-87-0 (2R,4S,5R)-2-Phenyl-4-((E)-styryl)-[1,3]dioxan-5-ol 
• 115997-87-0 (2R,4S,5R)-2-Phenyl-4-((Z)-styryl)-[1,3]dioxan-5-ol 
• 133782-90-8 (2R,4S,5R)-5-hydroxy-2-phenyl-4-vinyl-1,3-dioxane 

Relevant academic research and scientific papers

ERYTHROSE SESQUI-ACETALS AS ELECTROPHILES. 2-DEOXY-C-NUCLEOSIDES FROM D-GLUCOSE.

Cleavage of glucosides with NaIO4 in MeOH furnishes sesqui-acetals (protected dialdehydes).Olefination of these substrates, followed by endocyclic oxymercuration-demercuration furnishes substituted tetrahydrofurans (1,2-dideoxy-1-aryl-D-ribofuranoses).Pro

Structure and reactions of amino- and nitro-heptoseptanosides obtained by cyclization of dialdehydes with nitromethane

Base-catalyzed addition of nitromethane to the 2-ethyl hemialdal 3, resulting from the reversible addition of ethanol to the dialdehyde 2 obtained from NaIO4 oxidation of methyl 4,6-O-benzylidene-α-D-glucopyranoside (1) in aqueous solution, yie