137709-23-0Relevant academic research and scientific papers
Doubly-Strapped Porphyrins as Useful Building Blocks for Selectively Metallated Oligoporphyrins
Osuka, Atsuhiro,Nagata, Toshi,Maruyama, Kazuhiro
, p. 1687 - 1690 (1991)
Metallation of a porphyrin ring was completely suppressed by introducing two (CH2)10 "straps" on the both sides of the porphyrin ring.Di- and triporphyrins with one "doubly-strapped" ring were quantitatively converted to the partially metallated product w
Synthesis and Characterization of Doubly-Strapped Porphyrins
Nagata, Toshi
, p. 385 - 391 (2007/10/02)
Synthesis of a "doubly-strapped" porphyrin is described, which has two -O(CH2)10O- straps on both sides of the porphyrin ring.This porphyrin did not form the zinc complex when treated with zinc acetate, even under forcing conditions.Such inertness toward
