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Doubly-Strapped Porphyrins as Useful Building Blocks for Selectively Metallated Oligoporphyrins

DOI: 10.1246/cl.1991.1687

Source and publish data:

Chemistry Letters p. 1687 - 1690 (1991)

Update date:2022-08-06

Topics:

Authors:

Osuka, AtsuhiroOsuka, Atsuhiro

Nagata, ToshiNagata, Toshi

Maruyama, KazuhiroMaruyama, Kazuhiro

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Article abstract of DOI:10.1246/cl.1991.1687

Metallation of a porphyrin ring was completely suppressed by introducing two (CH2)10 "straps" on the both sides of the porphyrin ring.Di- and triporphyrins with one "doubly-strapped" ring were quantitatively converted to the partially metallated product w

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Full text of DOI:10.1246/cl.1991.1687

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