1377585-53-9

Basic information

• Product Name: N-[2-(methyl)-benzoyl]-S-methyl-S-4-(methyl)-phenyl sulfoximine
• Synonyms: N-[2-(methyl)-benzoyl]-S-methyl-S-4-(methyl)-phenyl sulfoximine
• CAS NO: 1377585-53-9
• Molecular Weight: 287.382
• Mol File: 1377585-53-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[2-(methyl)-benzoyl]-S-methyl-S-4-(methyl)-phenyl sulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[2-(methyl)-benzoyl]-S-methyl-S-4-(methyl)-phenyl sulfoximine(1377585-53-9)
• EPA Substance Registry System: N-[2-(methyl)-benzoyl]-S-methyl-S-4-(methyl)-phenyl sulfoximine(1377585-53-9)

Safety Data

• Hazardous Substances Data: 1377585-53-9(Hazardous Substances Data)

Upstream product

• 20414-85-1 S-methyl-S-(p-tolyl)sulfoximine 
• 933-88-0 ortho-toluoyl chloride 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 623-13-2 4-methylphenyl methylsulfide 

Downstream Products

• 1377585-23-3 N-[2-acetoxy-6-methylbenzoyl]-S-methyl-S-4-(methyl)phenylsulfoximine 

Relevant articles and documents

Sulfoximines: A reusable directing group for chemo-and regioselective ortho C-H oxidation of arenes

Sulfoximines direct: A new protocol for the chemo-and regioselective ortho C-H acetoxylation of arenes in N-benzoylated sulfoximines is reported. The sulfoximine directing group is easily detached from the C-H oxidation product through acid-promoted hydrolysis, isolated, and reused (see scheme). The meta-substituted phenols are synthesized following this strategy and the stereointegrity of the sulfoximine is preserved in this transformation. C(sp3)-H acetoxylation of the methyl group is also demonstrated.