137775-70-3

Basic information

• Product Name: (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol
• Synonyms: (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol
• CAS NO: 137775-70-3
• Molecular Weight: 275.261
• Mol File: 137775-70-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol(137775-70-3)
• EPA Substance Registry System: (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol(137775-70-3)

Safety Data

• Hazardous Substances Data: 137775-70-3(Hazardous Substances Data)

Upstream product

• 138145-77-4 (1S,4R,7S,8S)-(+)-7,8-O-Isopropylidenedioxy-2-oxa-3-azabicyclo<2.2.2>oct-5-ene hydrochloride 
• 137775-67-8 (1S,4R,5S,6R)-(-)-4-Amino-5,6-O-isopropylidenedioxycyclohex-2-en-1-ol 
• 80409-75-2 cis-2,2-dimethyl-3a,7a-dihydrobenzo[1,3]dioxole 
• 22509-74-6 N-ethoxycarbonylphthalimide 
• 137775-69-0 (1S,4R,5S,6R)-(-)-5,6-Isopropylidenedioxy-4-phthalimidocyclohex-2-enol 

Downstream Products

• 137775-71-4 (3S,4R,5S,6R)-(-)-3,4,5-Tris-6-phthalimidocyclohexene 
• 6730-25-2 (-)-1L-2,4-Diamino-2,4-dideoxychiroinositol dihydrochloride 

Relevant articles and documents

Asymmetric Synthesis of cis-1,3-Diamino-1,3-dideoxycyclitols

Starting with the hetero-Diels-Alder reaction of the O-isopropylidene-protected cis-cyclohexa-3,5-diene-1,2-diol with (-)-2,3:5,6-di-O-isopropylidene-1-nitroso-α-D-manno-furanosyl chloride the optically pure (+)-endo-adduct was exclusively formed.After re