6730-25-2

Upstream product

• 131682-28-5 1L-1,5-diamino-1,5-dideoxy-allo-inositole-hexaacetate 
• 131603-45-7 (1S,2R,3S,4S,5R,6S)-2,3,4-triacetoxy-5-(Z-2'-cyano-2'-tert-butylmercaptoethenyl)amino-7-oxabicyclo<4.1.0>heptane 
• 131603-46-8 (1S,2R,3R,4R,5S,6R)-1,2,3,5-tetraacetoxy-4-acetylamino-6-(Z-2'-cyano-2'-tert-butylmercaptoethenyl)aminocyclohexane 
• 131603-43-5 (1S,2S,4S,5R,6S,7R)-5,6-diacetoxy-8-(2'-cyano-2'-tert-butylmercaptoethenyl)-8-aza-3-oxatricyclo<5.1.0.0^2,4>octane 
• 137775-74-7 (1S,2S,3R,4S,5S,6S)-(-)-2-Acetoxy-3-phthalimido-4,5-bis-(trichloroacetimidato)-8-trichloromethyl-7-oxa-9-azabicyclo<4.3.0>non-8-ene 
• 80409-75-2 cis-2,2-dimethyl-3a,7a-dihydrobenzo[1,3]dioxole 
• 137775-67-8 (1S,4R,5S,6R)-(-)-4-Amino-5,6-O-isopropylidenedioxycyclohex-2-en-1-ol 
• 137775-70-3 (1S,2R,3S,6R)-(-)-6-Phthalimidocyclohex-4-ene-1,2,3-triol 
• 137775-69-0 (1S,4R,5S,6R)-(-)-5,6-Isopropylidenedioxy-4-phthalimidocyclohex-2-enol 
• 137775-72-5 (1S,2S,4S,5R,6S)-(-)-4,5-Epoxy-6-phthalimidocyclohexane-1,2,3-triol 
• 137775-73-6 (1S,2S,3S,4R,5R,6R)-(-)-4,5-Epoxy-6-phthalimidocyclohexane-1,2,3-triyl tristrichloroacetimidate 
• 137775-71-4 (3S,4R,5S,6R)-(-)-3,4,5-Tris-6-phthalimidocyclohexene 
• 138145-77-4 (1S,4R,7S,8S)-(+)-7,8-O-Isopropylidenedioxy-2-oxa-3-azabicyclo<2.2.2>oct-5-ene hydrochloride 

Relevant academic research and scientific papers

Asymmetric Synthesis of cis-1,3-Diamino-1,3-dideoxycyclitols

Starting with the hetero-Diels-Alder reaction of the O-isopropylidene-protected cis-cyclohexa-3,5-diene-1,2-diol with (-)-2,3:5,6-di-O-isopropylidene-1-nitroso-α-D-manno-furanosyl chloride the optically pure (+)-endo-adduct was exclusively formed.After re

SYNTHESIS OF CHIRAL AMINOCYCLITOLS VIA EPOXYEPIMINATION

Asymmetric Hetero-Diels-Alder reactions of cyclohexadienes 1 and (+/-)2 with the α-chloronitroso derivative of D-mannose 6 give the chiral dihydrooxazines 3-5.After N-functionalisation with the chloro-olefin 10 the N-vinyl-dihydrooxazines 11-13 thermally