13792-29-5Relevant academic research and scientific papers
A simple and new method for the synthesis of thiophosphates
Kaboudin, Babak
, p. 8713 - 8714 (2002)
A simple, efficient, and general method has been developed for the synthesis of thiophosphates through a one-pot reaction of alkyl halides with the mixture of diethyl phosphite in the presence of ammonium acetate/sulfur and acidic alumina under solvent-fr
Photoinduced Decarboxylative Phosphorothiolation of N-Hydroxyphthalimide Esters
Guo, Yu,Luo, Ying,Mu, Shiqiang,Xu, Jian,Song, Qiuling
, p. 6729 - 6734 (2021/09/11)
A visible-light-induced protocol for the synthesis of phosphorothioates is developed by employing the Ir-catalyzed decarboxylative phosphorothiolation of N-hydroxyphthalimide esters. This novel synthesis method utilizes carboxylic acids as raw material, which is stable, cheap, and commercially available. Scope studies show that this reaction has good compatibility of functional groups. Notably, both the synthesis of steric hindrance phosphorothioates and the later modification of some bioactive compounds are successfully achieved.
