137934-95-3Relevant academic research and scientific papers
An efficient protocol for the oxidative hydrolysis of ketone SAMP hydrazones employing SeO2 and H2O2 under buffered (pH 7) conditions
Smith III, Amos B.,Liu, Zhuqing,Simov, Vladimir
scheme or table, p. 3131 - 3134 (2010/03/24)
An effective oxidative protocol for the liberation of ketones from SAMP hydrazones employing peroxyselenous acid under aqueous buffered conditions (pH 7) has been developed. The procedure proceeds without epimerization of adjacent stereocenters or dehydration, in representative SAMP alkylation and aldol reaction adducts, respectively.
Regioselective oxidation of azidodiols, bromodiols and triol derivatives by dimethyldioxirane
Bovicelli, Paolo,Truppa, Danilo,Sanetti, Anna,Bernini, Roberta,Lupattelli, Paolo
, p. 14301 - 14314 (2007/10/03)
Azidodiols, bromodiols and triol derivatives were regioselectively monooxidised to the corresponding ketols using dimethyldioxirane. This regioselectivity is essentially determined by dipolar functionalities close to the potential reactive carbinol. These results make the reactivity of polyols with dimethyldioxirane highly predictable.
Acid Catalyzed Alcoholysis of an Epoxide and Reactions of Products on Contact with Silica Gel
Habermehl, Gerhard G.,Wippermann, Irene
, p. 1421 - 1424 (2007/10/02)
The alcoholysis of epoxide 1 in acidic methanol leads to various products; one of these - hydroxymethoxyketone 7 - rearranges to the isomeric ketone 14 on contact with silica gel. Keywords: Cleavage of Epoxide, Rearrangement
