138023-47-9

Basic information

• Product Name: 3,6-bis(trimethylsilyl)-1,8-diazatricyclo[6.2.2.0~2,7~]dodeca-2,4,6-triene
• Synonyms: 3,6-bis(trimethylsilyl)-1,8-diazatricyclo[6.2.2.0~2,7~]dodeca-2,4,6-triene
• CAS NO: 138023-47-9
• Molecular Formula: C16H28N2Si2
• Molecular Weight: 304.57792
• Mol File: 138023-47-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,6-bis(trimethylsilyl)-1,8-diazatricyclo[6.2.2.0~2,7~]dodeca-2,4,6-triene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-bis(trimethylsilyl)-1,8-diazatricyclo[6.2.2.0~2,7~]dodeca-2,4,6-triene(138023-47-9)
• EPA Substance Registry System: 3,6-bis(trimethylsilyl)-1,8-diazatricyclo[6.2.2.0~2,7~]dodeca-2,4,6-triene(138023-47-9)

Safety Data

• Hazardous Substances Data: 138023-47-9(Hazardous Substances Data)

Upstream product

• 7140-45-6 Benzo<1',2'-b>-1,4-diazabicyclo<2.2.2>octene 
• 75-77-4 chloro-trimethyl-silane 
• 135309-49-8 3'-Lithiobenzo<1',2'-b>-1,4-diazabicyclo<2.2.2>octene 

Relevant articles and documents

DIAZOBICYCLOALKANES WITH NITROGEN ATOM IN THE NODAL POSITIONS. 21. HETEROATOM-PROMOTED LITHIATION OF BENZO-1,4-DIAZABICYCLOOCTENE AND INTRODUCTION OF SUBSTITUENTS INTO THE ANNELATED BENZENE RING

The action of n-butyllithium on benzo-1,4-diazabicyclooctene leads to lithiation in the 3' position of the aromatic ring.The reaction of this lithium derivative with electrophilic reagents was used to synthesize 3'- and 3',6'-substituted derivatives of benzo-1,4-diazabicyclooctane.