1380328-46-0

Basic information

• Product Name: BrPd(C₆H₄CN)(P(C₁₀H₁₅)2C₆H₂(OCH₃)2C₆H₂(CH(CH₃)2)3)
• CAS NO: 1380328-46-0
• Molecular Weight: 929.369
• Mol File: 1380328-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: BrPd(C₆H₄CN)(P(C₁₀H₁₅)2C₆H₂(OCH₃)2C₆H₂(CH(CH₃)2)3)(CAS DataBase Reference)
• NIST Chemistry Reference: BrPd(C₆H₄CN)(P(C₁₀H₁₅)2C₆H₂(OCH₃)2C₆H₂(CH(CH₃)2)3)(1380328-46-0)
• EPA Substance Registry System: BrPd(C₆H₄CN)(P(C₁₀H₁₅)2C₆H₂(OCH₃)2C₆H₂(CH(CH₃)2)3)(1380328-46-0)

Safety Data

• Hazardous Substances Data: 1380328-46-0(Hazardous Substances Data)

Upstream product

• 225931-80-6 bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II) 
• 623-00-7 4-bromobenzenecarbonitrile 
• 1160861-59-5 2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl 

Relevant articles and documents

A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles

The incredible bulk: The first palladium-catalyzed amidation of five-membered heterocyclic bromides with multiple heteroatoms was achieved using the Pd/1 catalyst system. N-Arylated imidazoles, pyrazoles, thiazoles, pyrroles, and thiophenes were synthesized in moderate to excellent yield. Experimental results and DFT calculations point to the need for an electron-rich and sterically demanding biaryl phosphine ligand to promote these difficult reactions. Copyright