138124-94-4

Upstream product

• 136713-26-3 5-endo-Acetoxy-7-anti-phenylthiobicyclo<2.2.1>heptan-2-one 
• 57708-93-7 3-endo-Acetoxy-2-exo-bromobicyclo<3.2.0>heptan-6-one 
• 35553-68-5 Acetic acid (1R,2R,4R)-5-hydroxy-bicyclo[2.2.1]hept-2-yl ester 
• 5257-38-5 5-endo-Acetoxybicyclo<2.2.1>heptan-2-one 
• 100-39-0 benzyl bromide 
• 58029-22-4 5-endo-Hydroxybicyclo<2.2.1>heptan-2-one 
• 57260-95-4 (2S,3S,5R,7R)-3-Bromo-tricyclo[3.2.0.0^2,7]heptan-6-one 
• 137956-40-2 (1S,4S,5R)-Spiroheptan-2,2'-<1,3>dioxane>-5-ol 
• 137956-39-9 (1S,4S,5S)-5-Bromospiroheptan-2,2'-<1,3>dioxane> 
• 138125-10-7 (1S,2S,4S,5S)-5-Bromobicyclo<2.2.1>heptan-2-ol 
• 128111-35-3 (1S,4S,5S)-5-Bromobicyclo<2.2.1>heptan-2-one 
• 5888-36-8 (rac)-(exo,exo)-bicyclo[2.2.1]heptane-2,5-diol 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 909911-88-2 (1S,4S,5R)-5-hydroxybicyclo<2.2.1>heptane-2-one 

Downstream Products

• 136713-45-6 (1R,5R,6R)-6-Benzyloxy-3-oxa-bicyclo[3.2.1]octan-2-one 
• 136713-30-9 5-endo-Benzyloxy-2-ethylydenebicyclo<2.2.1>heptane 
• 137956-70-8 (1S,3R,5RS,7S,8R,9R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-9-ol methanesulphonate 
• 137956-61-7 (1S,4S,5R)-5-Hydroxybicyclo<2.2.1>heptan-2-one R-(+)-α-methoxy-α-(trifluoromethyl)phenylacetate 
• 130486-17-8 (1S,3R,5RS,7S,8R,9R)-9-Benzyloxy-7-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dioxatricyclo<6.2.1.0^3,7>undecane 
• 137956-43-5 (1S,3R,5RS,7S,8R,9S,11S)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4,10-trioxatetracyclo<6.3.1.0^3,7.0^9,11>dodecane 
• 130486-16-7 (1S,3R,5RS,7S,8R,9R)-9-Benzyloxy-7-(tert-butyldimethylsilyloxy)-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-5-ol 
• 137956-52-6 (1S,3R,5RS,7S,8R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undec-9-ene 
• 137956-51-5 (1S,3R,5RS,7S,8R,9R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-9-ol 
• 137956-71-9 (2RS,4S,1'R,2'S,4'S)-4-(tert-Butyldimethylsilyloxy)-4-(2-benzyloxy-4-hydroxypentyl)tetrahydrofuran-2-ol 
• 128849-68-3 (1S,4RS,5R,6R)-6-Benzyloxy-4-(tert-butyldimethylsilyloxy)-2-oxabicyclo<3.2.1>octan-3-one 
• 137956-67-3 (1R,3R,5RS,7S,8S)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecane 
• 130504-30-2 (1S,4S,5R,6R)-6-Benzyloxy-4-(tert-butyldimethylsilyloxy)-4-(prop-2-enyl)-2-oxabicyclo<3.2.1>octan-3-one 
• 137956-41-3 (1S,3S,4S,5R,6R)-6-Benzyloxy-4-(tert-butyldimethylsilyloxy)-4-(prop-2-enyl)-2-oxabicyclo<3.2.1>octan-3-ol 

Relevant academic research and scientific papers

Enzymatic Baeyer-Villiger oxidations of some bicycloheptan-2-ones using monooxygenases from Pseudomonas putida NCIMB 10007: enantioselective preparation of a precursor of azadirachtin

Two monooxygenases MO1 (NADH dependent) and MO2 (NADPH dependent) isolated from Ps. putida NCIMB 10007 have been utilized as biocatalysts in Baeyer-Villiger oxidations.The former enzyme oxidized the racemic ketones 9, 10 and 14 into

A Study of the Regioselectivity of Oxygen Insertion in the Baeyer-Villiger Oxidation of Bicycloheptan-2-ones

Synthesis and Baeyer-Villiger oxidation of the series of bicyclic ketones 3 and 6 is described.The ratio of methine to methylene carbon migration in the oxidation was found to vary depending on the 5-endo and 7-anti substituents of the ketones.Possible re

Chemistry of insect antifeedants from Azadirachta indica (Part 8):1 Synthesis of hydroxydihydrofuran acetal fragments for biological evaluation and azadirachtin total synthesis studies

The work describes a unified strategy towards the preparation of model hydroxydihydrofuran acetal fragments (2) (3) and (45) common to the potent insect antifeedant and growth disruption agent azadirachtin (1). These units, along with other analogues, wer

CHEMISTRY OF INSECT ANTIFEEDANTS FROM AZADIRACHTA INDICA (PART 7): PREPARATION OF AN OPTICALLY PURE HYDROXYACETAL EPOXIDE RELATED TO AZADIRACHTIN.

Preparation of an optically pure hydroxyacetal epoxide (2) as a model compound of the potent antifeedant azadirachtin (1) is reported.