130504-30-2

Upstream product

• 130551-08-5 (1S,5S,6R)-6-Benzyloxy-2-oxabicyclo<3.2.1>octan-3-one 
• 138124-94-4 (1S,4S,5R)-5-Benzyloxybicyclo<2.2.1>heptan-2-one 
• 130486-15-6 (1S,5S,6R)-6-Benzyloxy-4-hydroxy-2-oxa-bicyclo[3.2.1]octan-3-one 
• 137956-40-2 (1S,4S,5R)-Spiroheptan-2,2'-<1,3>dioxane>-5-ol 
• 137956-39-9 (1S,4S,5S)-5-Bromospiroheptan-2,2'-<1,3>dioxane> 
• 138125-10-7 (1S,2S,4S,5S)-5-Bromobicyclo<2.2.1>heptan-2-ol 
• 100-39-0 benzyl bromide 
• 128111-35-3 (1S,4S,5S)-5-Bromobicyclo<2.2.1>heptan-2-one 
• 128849-68-3 (1S,4RS,5R,6R)-6-Benzyloxy-4-(tert-butyldimethylsilyloxy)-2-oxabicyclo<3.2.1>octan-3-one 
• 106-95-6 allyl bromide 
• 110354-77-3 (1R,4R,5R)-5-Benzyloxy-bicyclo[2.2.1]heptan-2-one 
• 130486-15-6 (1R,5R,6R)-6-Benzyloxy-4-hydroxy-2-oxa-bicyclo[3.2.1]octan-3-one 
• 128849-65-0 (1R,5R,6R)-6-Benzyloxy-2-oxa-bicyclo[3.2.1]octan-3-one 
• 909911-88-2 (1S,4S,5R)-5-hydroxybicyclo<2.2.1>heptane-2-one 

Downstream Products

• 137956-70-8 (1S,3R,5RS,7S,8R,9R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-9-ol methanesulphonate 
• 130486-17-8 (1S,3R,5RS,7S,8R,9R)-9-Benzyloxy-7-(tert-butyldimethylsilyloxy)-5-methoxy-2,4-dioxatricyclo<6.2.1.0^3,7>undecane 
• 137956-43-5 (1S,3R,5RS,7S,8R,9S,11S)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4,10-trioxatetracyclo<6.3.1.0^3,7.0^9,11>dodecane 
• 137956-52-6 (1S,3R,5RS,7S,8R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undec-9-ene 
• 137956-51-5 (1S,3R,5RS,7S,8R,9R)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-9-ol 
• 137956-67-3 (1R,3R,5RS,7S,8S)-7-(tert-Butyldimethylsilyloxy)-5-phenylseleno-2,4-dioxatricyclo<6.2.1.0^3,7>undecane 
• 137956-71-9 (2RS,4S,1'R,2'S,4'S)-4-(tert-Butyldimethylsilyloxy)-4-(2-benzyloxy-4-hydroxypentyl)tetrahydrofuran-2-ol 
• 130486-16-7 (1S,3R,5RS,7S,8R,9R)-9-Benzyloxy-7-(tert-butyldimethylsilyloxy)-2,4-dioxatricyclo<6.2.1.0^3,7>undecan-5-ol 
• 137956-42-4 (1S,3R,4R)-3-Benzyloxy-4-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-1-hydroxymethyl-but-3-enyl]-cyclopentanol 
• 137956-41-3 (1S,3S,4S,5R,6R)-6-Benzyloxy-4-(tert-butyldimethylsilyloxy)-4-(prop-2-enyl)-2-oxabicyclo<3.2.1>octan-3-ol 
• 130486-16-7 (1S,2S,6R,8R,10R)-10-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-5,7-dioxa-tricyclo[6.2.1.0^2,6]undecan-4-ol 
• 130486-17-8 ((1S,2S,6R,8R,10R)-10-Benzyloxy-4-methoxy-5,7-dioxa-tricyclo[6.2.1.0^2,6]undec-2-yloxy)-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Chemistry of insect antifeedants from Azadirachta indica (Part 8):1 Synthesis of hydroxydihydrofuran acetal fragments for biological evaluation and azadirachtin total synthesis studies

The work describes a unified strategy towards the preparation of model hydroxydihydrofuran acetal fragments (2) (3) and (45) common to the potent insect antifeedant and growth disruption agent azadirachtin (1). These units, along with other analogues, wer

CHEMISTRY OF INSECT ANTIFEEDANTS FROM AZADIRACHTA INDICA (PART 7): PREPARATION OF AN OPTICALLY PURE HYDROXYACETAL EPOXIDE RELATED TO AZADIRACHTIN.

Preparation of an optically pure hydroxyacetal epoxide (2) as a model compound of the potent antifeedant azadirachtin (1) is reported.