1381847-76-2Relevant academic research and scientific papers
Triphosgene/Sodium Organosulfinate System: A General and Efficient Electrophilic Thiolation of Silylenol Ethers and Electron-Rich Heteroaromatics
Gao, Hai-Jun,Gu, Yu-Xin,Wang, Zhe-Fei,Yuan, Yan-Qin,Wang, Yan,Guo, Sheng-Rong
, p. 1838 - 1842 (2020)
An efficient and practical approach to electrophilic thiolation was developed by using commercially available triphosgene as a reductant and the appropriate alkyl- or arylsulfinates, which were transformed in situ into electrophilic RSCl intermediates in the presence of triphosgene. This procedure represents a general and powerful approach for the synthesis of α-(trifluoromethyl)thio-substituted ketones and thiolated electron-rich heteroaromatic compounds.
Copper-catalyzed sulfenylation of pyrroles with disulfides or thiols: Directly synthesis of sulfenyl pyrroles
Alves, Diego,Lara, Renata G.,Contreira, Maria E.,Radatz, Cátia S.,Duarte, Luis F.B.,Perin, Gelson
experimental part, p. 3364 - 3368 (2012/07/28)
We present here the synthesis of sulfenyl pyrroles by copper-catalyzed sulfenylation of pyrroles with organic disulfides or thiols. The direct sulfenylation of pyrroles with organic disulfides has been accomplished in the presence of 3 mol % of CuI in DMS
