138258-77-2

Upstream product

• 474049-73-5 (S,S)-(-)-1-hydroxy-1-oxo-2,5-trans-diphenylphospholane 
• 226393-31-3 1-(N,N-dimethylamino)-1-r-oxo-2-t,5-t-diphenylphosphol-3-ene 
• 295328-90-4 (1R,4R)-1,4-bis(methanesulfonyloxy)-1,4-diphenylbutane 
• 226393-36-8 1-(N,N-dimethylamino)-1-r-oxo-2-t,5-t-diphenylphospholane 
• 474093-56-6 (S,S)-(-)-1-chloro-1-r-oxo-2-c,5-t-diphenylphospholane 
• 474093-57-7 (S,S)-(-)-1-r-oxo-2-c,5-t-diphenylphospholane 
• 591-51-5 phenyllithium 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 214280-56-5 (+)-(1R,4R)-1,4-diphenylbutane-1,4-diol 
• 495-71-6 phenacylacetophenone 
• 13595-56-7 dilithium phenylphosphide 
• 474093-54-4 (2S,5S)-(-)-1-r-oxo-1,2-c,5-triphenyl phospholane 

Downstream Products

• 474093-54-4 (2S,5S)-(-)-1-r-oxo-1,2-c,5-triphenyl phospholane 

Relevant academic research and scientific papers

P-aryl-diphenylphospholanes and their phospholanium salts as efficient monodentate ligands for asymmetric rhodium-catalyzed hydrogenation

Enantiopure P-aryl-2,5-diphenylphospholanes and its corresponding P-aryl-phospholanium salt appear as very efficient ligands for rhodium-catalyzed asymmetric hydrogenation reaction with similar activities and enantioselectivities. The hydrogenation product was obtained in good enantiomeric excesses (up to 93% ee ) in only few minutes under an atmospheric pressure of dihydrogen. The excellent activity of the catalyst can be explained by a constant and high TOF value during the reaction.

Olefination of ketenes for the enantioselective synthesis of allenes via an ylide route

Pseudo-C2-symmetric chiral phosphorus ylide is designed and synthesized for the enantioselective preparation of allenic esters, amides, ketone, and nitrile. Up to 92% ee is achieved.

Enantioselective synthesis of allenic esters via an ylide route

Pseudo-C2-symmetric chiral phosphorus ylides have been designed and synthesized for the enantioselective preparation of allenic esters, and up to 92% ee has been achieved. The Royal Society of Chemistry 2006.

Synthesis and first applications of a new family of chiral monophosphine ligand: 2,5-diphenylphosphospholanes

The cyclic phosphinic acid 1-hydroxy-1-r-oxo-2c,5-t-diphenylphospholane was synthesized and resolved into enantiomers through fractional crystallization of the quinine salts. The P-phenyl, P-methyl and P-benzyl tertiary phosphine oxides were obtained from