138260-01-2Relevant academic research and scientific papers
Convenient one-pot synthesis of tert-butyldimethylantimony
Gedridge Jr., Robert W.
, p. 967 - 969 (1992)
tert-Butyldimethylantimony, (t-Bu)Me2Sb, was prepared by a one-pot reaction of SbCl3 with 1 equiv of (t-Bu)MgCl at -50°C followed by 2 equiv of MeMgBr at 0°C in diethyl ether. (t-Bu)Me2Sb was isolated in 64% yield (based on SbCl3) after fractional vacuum distillation (63°C at 30 Torr) and can be used as a precursor in the chemical vapor deposition of antimony-containing semi-conductor materials.
