13830-40-5Relevant academic research and scientific papers
Synthesis of cyclopropylsilanols by the Simmons-Smith reaction of alkenylsilanols and lithium alkenylsilanolates
Hirabayashi, Kazunori,Mori, Atsunori,Hiyama, Tamejiro
, p. 461 - 464 (1997)
Alkenylsilanols and the corresponding lithium silanolates prepared in situ by the reaction of cyclic siloxanes with alkenyllithiums are transformed to the corresponding cyclopropylsilanols under the Simmons-Smith reaction conditions. The obtained cyclopropylsilanols are further converted into the corresponding cyclopropanols by the Tamao oxidation.
Exploiting the enantioselectivity of Baeyer-Villiger monooxygenases via boron oxidation
Brondani, Patricia B.,Dudek, Hanna,Reis, Joel S.,Fraaije, Marco W.,Andrade, Leandro H.
experimental part, p. 703 - 708 (2012/09/21)
The enantioselective carbon-boron bond oxidation of several chiral boron-containing compounds by Baeyer-Villiger monooxygenases was evaluated. PAMO and M446G PAMO conveniently oxidized 1-phenylethyl boronate into the corresponding 1-(phenyl)ethanol (ee = 82-91%). Cyclopropyl boronic esters were also oxidized but with no enantioselectivity. β-Boryl carboxylic esters were not oxidized by any BVMOs.
