138332-29-3Relevant academic research and scientific papers
Chemistry of insect antifeedants from Azadirachta indica (part 9): Oxidative reactions of azadirachtin derivatives leading to C8-C14 bond cleavage
Ley, Steven V.,Lovell, Peter J.,Smith, Stephen C.,Wood, Anthony
, p. 6183 - 6186 (1991)
A novel macrocyclic carbonate (4) was obtained by pyridinum chlorochromate oxidation of an azadirachtin derivative (3). This underwent efficient C8-C14 bond cleavage via a retro-Aldol reaction to give a highly functionalised decalin derivative (5) with po
Chemistry of Insect Antifeedants from Azadirachta indica, Part 14: Absolute Configuration of Azadirachtin
Ley, Steven V.,Lovell, Helen,Williams, David J.
, p. 1304 - 1306 (2007/10/02)
The absolute configuration of the insect antifeedant azadirachtin is determined by high field NMR application of the Mosher method and confirmed by X-ray crystallographic analysis.
