Chemistry of insect antifeedants from Azadirachta indica (part 9): Oxidative reactions of azadirachtin derivatives leading to C8-C14 bond cleavage

DOI: 10.1016/0040-4039(91)80784-4

Source and publish data:

Tetrahedron Letters p. 6183 - 6186 (1991)

Update date:2022-07-29

Topics:

Authors:

Ley, Steven V.

Lovell, Peter J.

Smith, Stephen C.

Wood, Anthony

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Article abstract of DOI:10.1016/0040-4039(91)80784-4

A novel macrocyclic carbonate (4) was obtained by pyridinum chlorochromate oxidation of an azadirachtin derivative (3). This underwent efficient C8-C14 bond cleavage via a retro-Aldol reaction to give a highly functionalised decalin derivative (5) with po

Full text of DOI:10.1016/0040-4039(91)80784-4

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