Tetrahedron Letters p. 6183 - 6186 (1991)
Update date:2022-07-29
Topics:
Ley, Steven V.
Lovell, Peter J.
Smith, Stephen C.
Wood, Anthony
A novel macrocyclic carbonate (4) was obtained by pyridinum chlorochromate oxidation of an azadirachtin derivative (3). This underwent efficient C8-C14 bond cleavage via a retro-Aldol reaction to give a highly functionalised decalin derivative (5) with po
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