1383537-01-6

Basic information

• Product Name: 4-methyl-2,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine
• CAS NO: 1383537-01-6
• Molecular Weight: 251.328
• Mol File: 1383537-01-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-methyl-2,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-2,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine(1383537-01-6)
• EPA Substance Registry System: 4-methyl-2,6-diphenyl-3,6-dihydro-2H-[1,2]oxazine(1383537-01-6)

Safety Data

• Hazardous Substances Data: 1383537-01-6(Hazardous Substances Data)

Upstream product

• 21919-51-7 3-methyl-1-phenyl-buta-1,3-diene 
• 100-65-2 N-Phenylhydroxylamine 
• 586-96-9 Nitrosobenzene 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 100-52-7 benzaldehyde 
• 58879-44-0 1-acetoxy-1-phenylbut-2-yne 
• 32398-66-6 1-phenylbut-2-yn-1-ol 
• 21020-31-5 3-methyl-1-phenyl-1,2-butadiene 

Relevant articles and documents

Copper-catalyzed pyrrole synthesis from 3,6-dihydro-1,2-oxazines

Highly-functionalized pyrroles could be effectively synthesized from 3,6-dihydro-1,2-oxazines using a heterogeneous copper on carbon (Cu/C) under neat heating conditions. Furthermore, the in situ formation of 3,6-dihydro-1,2-oxazines via the hetero Diels-Alder reaction between nitroso dienophiles and 1,3-dienes and the following Cu/C-catalyzed pyrrole synthesis also provided the corresponding pyrrole derivatives in a one-pot manner.

Gold-catalyzed isomerization of unactivated allenes into 1,3-dienes under ambient conditions

We have developed a gold-catalyzed isomerization of unactivated allenes into 1,3-dienes with nitrosobenzene as an additive. This reaction proceeded almost exclusively at room temperature for highly substituted allenes. The utility of this reaction is manifested by the development of one-pot [4+2]-cycloaddition of allenes and reactive alkenes.