138448-92-7Relevant academic research and scientific papers
Microbial oxidation of aromatics in enantiocontrolled synthesis. 3.1 design of amino cyclitols (exo-nitrogenous) and total synthesis of (+)-lycoricidine via acylnitrosyl cycloaddition to polarized 1-halo-1,3-cyclohexadienes
Hudlicky, Tomas,Olivo, Horacio F.,McKibben, Bryan
, p. 5108 - 5115 (2007/10/02)
Oxidation of halogenated benzenes with bacterial dioxygenase from Pseudomonas putida 39D (whole cell fermentation) provided homochiral 1,3-cyclohexadiene-cis-diols 1 for the entire halogen series. These compounds were investigated for their potential in c
Stereospecific synthesis of aminocyclitols via cycloadditions of unsymmetrical, optically pure dienes: Conduramine A-1 and Dihydroconduramine A-1
Hudlicky,Olivo
, p. 6077 - 6080 (2007/10/02)
Stereospecific synthesis of Conduramine A-1 and Dihydroconduramine A-1 has been achieved by a fully regio- and stereospecific hetero Diels-Alder cycloaddition of a nitrosyl derivative and homochiral 1-halocyclohexadiene diols obtained by microbial oxidati
Biocatalysis as the Strategy of Choice in the Exhaustive Enantiomerically Controlled Synthesis of Conduritols
Hudlicky, Tomas,Luna, Hector,Olivo, Horacio F.,Andersen, Catherine,Nugent, Thomas,Price, John D.
, p. 2907 - 2918 (2007/10/02)
An approach to several conduritols, both naturally occurring and unnatural derivatives, is described.The key strategy of this potentially exhaustive approach relies on the bio-oxidation of chloro- or bromo-benzene to their corresponding cis-diols.Subseque
