138513-22-1Relevant academic research and scientific papers
Asymmetric Synthesis of cis-1,3-Diamino-1,3-dideoxycyclitols
Schuerrle, Karsten,Beier, Barbara,Piepersberg, Wolfgang
, p. 2407 - 2412 (2007/10/02)
Starting with the hetero-Diels-Alder reaction of the O-isopropylidene-protected cis-cyclohexa-3,5-diene-1,2-diol with (-)-2,3:5,6-di-O-isopropylidene-1-nitroso-α-D-manno-furanosyl chloride the optically pure (+)-endo-adduct was exclusively formed.After re
Biocatalysis as the Strategy of Choice in the Exhaustive Enantiomerically Controlled Synthesis of Conduritols
Hudlicky, Tomas,Luna, Hector,Olivo, Horacio F.,Andersen, Catherine,Nugent, Thomas,Price, John D.
, p. 2907 - 2918 (2007/10/02)
An approach to several conduritols, both naturally occurring and unnatural derivatives, is described.The key strategy of this potentially exhaustive approach relies on the bio-oxidation of chloro- or bromo-benzene to their corresponding cis-diols.Subseque
Stereospecific synthesis of aminocyclitols via cycloadditions of unsymmetrical, optically pure dienes: Conduramine A-1 and Dihydroconduramine A-1
Hudlicky,Olivo
, p. 6077 - 6080 (2007/10/02)
Stereospecific synthesis of Conduramine A-1 and Dihydroconduramine A-1 has been achieved by a fully regio- and stereospecific hetero Diels-Alder cycloaddition of a nitrosyl derivative and homochiral 1-halocyclohexadiene diols obtained by microbial oxidati
