123808-78-6Relevant articles and documents
Stereospecific synthesis of aminocyclitols via cycloadditions of unsymmetrical, optically pure dienes: Conduramine A-1 and Dihydroconduramine A-1
Hudlicky,Olivo
, p. 6077 - 6080 (2007/10/02)
Stereospecific synthesis of Conduramine A-1 and Dihydroconduramine A-1 has been achieved by a fully regio- and stereospecific hetero Diels-Alder cycloaddition of a nitrosyl derivative and homochiral 1-halocyclohexadiene diols obtained by microbial oxidati
Asymmetric Synthesis of cis-1,3-Diamino-1,3-dideoxycyclitols
Schuerrle, Karsten,Beier, Barbara,Piepersberg, Wolfgang
, p. 2407 - 2412 (2007/10/02)
Starting with the hetero-Diels-Alder reaction of the O-isopropylidene-protected cis-cyclohexa-3,5-diene-1,2-diol with (-)-2,3:5,6-di-O-isopropylidene-1-nitroso-α-D-manno-furanosyl chloride the optically pure (+)-endo-adduct was exclusively formed.After re
Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, IV. - Preparation and Stereochemistry of Dideoxyinosamine Derivatives
Kresze, Guenter,Kysela, Ernst
, p. 202 - 209 (2007/10/02)
The general method for the synthesis of polyhydroxy amines by Diels-Alder reactions with a nitroso compound, reduction of the adduct with cleavage of the N - O bond and hydroxylation of the remaining C = C -double bond, can also be realized with α-chloronitrosocyclohexane as dienophile, in good yield.Primary amines are synthesized in this way.