138485-29-7

Basic information

• Product Name: DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE
• Synonyms: RARECHEM AL BF 1335;DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE;DiMethyl 2-(3-(trifluoroMethyl)phenyl)Malonate
• CAS NO: 138485-29-7
• Molecular Formula: C₁₂H₁₁F₃O₄
• Molecular Weight: 276.21
• Mol File: 138485-29-7.mol

Chemical Properties

• Boiling Point: 266.8±35.0 °C(Predicted)
• Appearance: /
• Density: 1.296±0.06 g/cm3(Predicted)
• PKA: 10.98±0.59(Predicted)
• CAS DataBase Reference: DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE(138485-29-7)
• EPA Substance Registry System: DIMETHYL-(3-(TRIFLUOROMETHYL)-PHENYL)-MALONATE(138485-29-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 138485-29-7(Hazardous Substances Data)

Upstream product

• 553-90-2 Dimethyl oxalate 
• 62451-84-7 (3-trifluoromethyl-phenyl)-acetic acid methyl ester 
• 351-35-9 3-(trifluoromethyl)phenylacetic acid 
• 120276-50-8 1-(iodomethyl)-3-(trifluoromethyl)benzene 
• 108-59-8 malonic acid dimethyl ester 
• 401-81-0 m-trifluoromethylphenyl iodide 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 1383916-52-6 bis(2,4,6‐trichlorophenyl)-2‐(3‐(trifluoromethyl)phenyl)malonate 
• 1263133-33-0 3,4-dihydro-2,4-dioxo-1-(pyrimidin-5-ylmethyl)-3-(α,α,α-trifluoro-m-tolyl)-2H-pyrido[1,2-a]pyrimidin-1-ium-3-ide 
• 1443330-15-1 2-[3-(trifluoromethyl)phenyl]propanedioyl dichloride 
• 138485-61-7 4-Hydroxy-6-methyl-3-(3-trifluoromethyl-phenyl)-1H-pyridin-2-one 
• 145983-07-9 α-methyl-α-(m-trifluoromethylphenyl)malonic acid 
• 150360-28-4 (R)-2-(3-Trifluoromethyl-phenyl)-propionic acid 
• 138485-34-4 4-Hydroxy-2-methyl-6-oxo-5-(3-trifluoromethyl-phenyl)-1,6-dihydro-pyridine-3-carboxylic acid ethyl ester 

Relevant articles and documents

Discovery of Novel Benzo[4,5]thiazolo(oxazolo)[3,2-a]pyrimidinone Mesoionic Derivatives as Potential Antibacterial Agents and Mechanism Research

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Pyrimidinium compound, and preparation method and application thereof

The invention relates to a pyrimidinium compound, and a preparation method and an application thereof, and concretely relates to a pyrimidinium compound represented by formula (B2-A) or a stereoisomer, a nitrogen oxide and a salt thereof, an application of the above compounds as insecticides in agriculture, a form of an insecticide composition of the compound, and a method for controlling pests byusing the compounds or the composition. In the formula (B2-A), U, L, R, R, R, R, R, R, R, o and w have the meanings described in the invention.

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Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes

A gold(I)-catalyzed enantioselective desymmetrization of 1,3-diols was achieved by intramolecular hydroalkoxylation of allenes. The catalyst system 3-F-dppe(AuCl)2 /(R)-C8-TRIPAg proved to be specifically efficient to promote the desymmetrizing cyclization of 2-aryl-1,3-diols, which have proven challenging substrates in previous reports. Multisubstituted tetrahydrofurans were prepared in good yield with good enantioselectivity and diastereoselectivity by this method.

MALONIC ACID DI-SALTS AND A METHOD FOR PREPARING MALONYL DIHALIDES

A compound of Formula (2) is disclosed: wherein R1, MA and MB are as defined in the disclosure. Also disclosed is a method for preparing a compound of Formula (1): wherein R1 and X are as defined in the disclosure comprising contacting a compound of Formula (2) with a halogenating agent. Also disclosed is a method for preparing a compound of Formula (4): wherein R1, R3 and R4 are as defined in the disclosure, comprising reacting a compound of Formula (5): wherein R3 and R4 are as defined in the disclosure with a compound of Formula (1), with a compound of Formula (1), the process of preparing the compound of Formula (4) includes the step of preparing the compound of Formula (1) from the compound of Formula (2) by the method disclosed above. Also disclosed is compound that is methyl 3,5-dichlorobenzeneethanimidate methyl 3,5 dichlorobenzeneethanimidate or ethyl 3,5 dichlorobenzeneethanimidate or salts thereof.