1384881-43-9

Basic information

• Product Name: C₂₉H₄₁NO₆Si
• Synonyms: C₂₉H₄₁NO₆Si
• CAS NO: 1384881-43-9
• Molecular Weight: 527.733
• Mol File: 1384881-43-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₉H₄₁NO₆Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₉H₄₁NO₆Si(1384881-43-9)
• EPA Substance Registry System: C₂₉H₄₁NO₆Si(1384881-43-9)

Safety Data

• Hazardous Substances Data: 1384881-43-9(Hazardous Substances Data)

Upstream product

• 364631-72-1 tert-butyl N-[5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxan-5-yl]carbamate 
• 364631-73-2 tert-butyl 5-formyl-2,2-dimethyl-1,3-dioxan-5-ylcarbamate 
• 146651-71-0 N-(tert-butyloxycarbonyl)-2-amino-2-(hydroxymethyl)propane-1,3-diol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 1384881-36-0 C₃₂H₄₅NO₆Si 

Downstream Products

• 1384881-44-0 C₄₁H₆₉NO₆Si₃ 

Relevant articles and documents

Stereoselective functionalization of pyrrolidinone moiety towards the synthesis of salinosporamide A

An important feature of the synthesis of salinosporamide A, a potent proteasome inhibitor, is the establishment of the quaternary stereocenter at C3. A new route has been developed based on the methylation of a functionalized pyrrolidinone. Direct methylation reaction led to the unwanted diastereomer; however, by means of a Corey-Chaykovsky reaction followed by LiAlH4 epoxide opening, the desired alcohol was obtained. The pyrrolidinone was elaborated through a key allylation reaction between a tertiary allyltitanium reagent and an aldehyde bearing a spiroketal moiety in α-position.