138495-02-0Relevant academic research and scientific papers
Nitrogen-Doped Carbon Enables Heterogeneous Asymmetric Insertion of Carbenoids into Amines Catalyzed by Rhodium Nanoparticles
Kobayashi, Shū,Masuda, Ryusuke,Yamashita, Yasuhiro,Yasukawa, Tomohiro
supporting information, p. 12786 - 12790 (2021/05/07)
Development of stable heterogeneous catalyst systems is a crucial subject to achieve sustainable society. Though metal nanoparticles are robust species, the study of asymmetric catalysis by them has been restricted because methods to activate metal nanopa
Molecular iodine catalyzed transfer hydrogenation: Reduction of aldimines, ketimines, and α-imino esters
Bachu, Prabhakar,Zhu, Chen,Akiyama, Takahiko
supporting information, p. 3977 - 3981 (2013/07/25)
An efficient and practical protocol for the reduction of aldimines, ketimines, and α-imino esters in the presence of catalytic amount of molecular iodine with Hantzsch ester at ambient temperature afforded the corresponding amines in excellent yields.
A novel four-component synthesis of N-substituted amino acid esters
Henkel, Bernd,Weber, Lutz
, p. 1877 - 1879 (2007/10/03)
A library of N-substituted amino acid esters was synthesized using a solid phase bound organic isocyanide that provides a C1 synthon to the final molecule. This novel four-component, one-pot reaction delivers the final products in acceptable yields with high purities of the crude reaction products, facilitating the final purification. The preparation of the isocyano resin is also described the intermediates being controlled by ATR-spectroscopy.
Electroreductive Coupling of Aromatic Imines with Electrophiles in the Presence of Chlorotrimethylsilane
Shono, Tatsuya,Kise, Naoki,Kunimi, Nobutaka,Nomura, Ryoji
, p. 2191 - 2194 (2007/10/02)
Electroreduction of aromatic imines in the presence of electrophiles gave the corresponding inter- and intramolecular coupling products when the reaction was carried out with the use of chlorotrimethylsilane (CTMS) as the trapping agent of an anion interm
