138512-07-9Relevant academic research and scientific papers
Enantioselective construction of cis-2,6-disubstituted dihydropyrans: Total synthesis of (-)-centrolobine
Chaladaj, Wojciech,Kowalczyk, Rafa,Jurczak, Janusz
supporting information; experimental part, p. 1740 - 1743 (2010/05/18)
(Chemical Equation Presentation) This paper presents a simple and efficient route to chiral cis-6-substituted 2-(2-hydroxyethyl)-5,6-dihydro-2H-pyrans, a versatile chiral building block. The strategy is based on three key transformations: enantioselective
A route to artificial glycoconjugates and oligosaccharides via enzymatically resolved glycals: Dramatic effects of the handedness of the sugar domain upon the properties of an anthracycline drug
Berkowitz, David B.,Danishefsky, Samuel J.,Schulte, Gayle K.
, p. 4518 - 4529 (2007/10/02)
Racemic, fully synthetic glycals of considerable structural variety may be kinetically resolved via enzymatically mediated transesterification using Lipase PS-30 from Pseudomonas cepacia as catalyst and vinyl acetate as acyl donor. This methodology provid
Enzymatic resolution of racemic glycals: An application of the wong acylation method
Berkowitz,Danishefsky
, p. 5497 - 5500 (2007/10/02)
Kinetic resolution of racemic, fully synthetic, artificial glycals bearing a free hydroxyl group at C3 was accomplished through the more rapid acylation of the 'D'-antipode with vinyl acetate as acyl donor and Lipase PS-30 from Pseudomonas cepa
Stereoselective C-Glycosidation of Glycals with Organoaluminum Reagents
Maruoka, Keiji,Nonoshita, Katsumasa,Itoh, Takayuki,Yamamoto, Hisashi
, p. 2215 - 2216 (2007/10/02)
A new approach to the stereoselective synthesis of C-glycosides from glycals with various organoaluminum reagents has been demonstrated.
