138521-71-8

Basic information

• Product Name: Mn(N(CH₂CH₂NCHC₆H₃(4-Me)O)3)
• Synonyms: Mn(N(CH₂CH₂NCHC₆H₃(4-Me)O)3)
• CAS NO: 138521-71-8
• Molecular Weight: 552.555
• Mol File: 138521-71-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn(N(CH₂CH₂NCHC₆H₃(4-Me)O)3)(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(N(CH₂CH₂NCHC₆H₃(4-Me)O)3)(138521-71-8)
• EPA Substance Registry System: Mn(N(CH₂CH₂NCHC₆H₃(4-Me)O)3)(138521-71-8)

Safety Data

• Hazardous Substances Data: 138521-71-8(Hazardous Substances Data)

Upstream product

• 35638-41-6 tetra-n-butylammonium permanganate 
• 6156-78-1 manganese (II) acetate tetrahydrate 
• 138805-06-8 tris-(2-(2-hydroxy-4-methylbenzylideneamino)ethyl)amine 

Relevant articles and documents

Manganese(III) Complexes with MnIIIN3O3 (S = 2) Co-ordination by Sexidentate Schiff-base Ligands: Synthesis, Spectra and Electrochemistry

Complexes of high-spin manganese(III) (μeff = 4.79-5.30 at 298 K) with a closely related group of sexidentate Schiff-base ligands have been prepared and their solution properties thoroughly investigated.The brown to green crystalline complexes display ligand-to-metal charge-transfer transitions in the range 330-400 nm in addition to a crystal-field transition in the range 560-600 nm.The solution stereochemistry has been determined by paramagnetically shifted 1H NMR spectroscopy.Unlike the C3 symmetry in the solid-state structure, in solution the MnIIIN3O3 co-ordination sphere is severely distorted (ca.C1 symmetry).Cyclic voltammetric studies in dimethylformamide solution reveal an irreversible MnIII-MnII couple pc in the range -0.62 to -0.05 V vs. saturated calomel electrode (SCE)> and a quasi-reversible MnIV-MnIII couple (Ef in the range +0.42 to +0.86 V vs.SCE).