138536-08-0Relevant academic research and scientific papers
Non-oxidative Conversion of Ketone Carbonyls into Carboxy Carbonyls. Comparison of 2-Acylthiazoles and 2-Acylimidazoles in the Aldol Condensation and the Stereospecific Cleavage of an Example of the Latter to a β-Hydroxy Ester via the Azolium Salt
Davies, D. Huw,Hall, Jonathan,Smith, Edward H.
, p. 2691 - 2698 (2007/10/02)
The synthesis of some 2-acyl-thiazoles and -imidazoles is described.In the subsequent aldol condensation of these ketones, the imidazole congeners were much better behaved.N-Methylation of the imidazole aldols was only partially successful and suffered fr
