138638-93-4

Basic information

• Product Name: Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside
• Synonyms: Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside
• CAS NO: 138638-93-4
• Molecular Weight: 546.779
• Mol File: 138638-93-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside(138638-93-4)
• EPA Substance Registry System: Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside(138638-93-4)

Safety Data

• Hazardous Substances Data: 138638-93-4(Hazardous Substances Data)

Upstream product

• 55610-71-4 methyl (methyl-2,3,4-tri-O-benzyl-α-D-glucopyranosid)uronate 
• 120444-48-6 (2S,3S,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-methoxytetrahydro-2H-pyran-2-carboxylic acid 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 138638-92-3 Methyl 2,3,4-tri-O-benzyl-6-bis-C-<(trimethylsilyl)methyl>-α-D-glucopyranoside 

Downstream Products

• 138639-02-8 Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside 

Relevant articles and documents

A one-step C-linked disaccharide synthesis from carbohydrate allylsilanes and tri-O-acetyl-D-glucal

The reaction of protected glucuronic esters 2 and 7, as well as D-glucuronolactone derivative 11, with (trimethylsilyl)methylmagnesium chloride in ether led to the corresponding stable bis-silyl adducts 3, 8, and 12, respectively. In Peterson-type reactio