55610-71-4

Upstream product

• 186581-53-3 diazomethane 
• 120444-48-6 (2S,3S,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-methoxytetrahydro-2H-pyran-2-carboxylic acid 
• 75336-65-1 methyl 2,3,4-tri-O-benzyl-α-D-glucopyranuronate 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 67-56-1 methanol 
• 83051-88-1 methyl 6-aldehydo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 75336-63-9 methyl <2,3,4-tri-O-benzyl-α-D-glucopyranosyl chloride>uronate 
• 75336-64-0 (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-chloro-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 75336-62-8 Methyl 2,3,4-tri-O-benzyl-1-bromo-1-deoxy-D-glucopyranuronate 

Downstream Products

• 957375-03-0 methyl 2,3,4,6-tetra-O-benzyl-α-D-[6-2H₂]glucopyranoside 
• 142742-76-5 methyl 2,3,4-tri-O-benzyl-α-D-[6-2H₂]glucopyranoside 
• 138638-92-3 Methyl 2,3,4-tri-O-benzyl-6-bis-C-<(trimethylsilyl)methyl>-α-D-glucopyranoside 
• 138639-02-8 Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside 
• 138638-93-4 Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside 
• 138638-94-5 Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methyl-α-D-gluco-hept-6-eno-1,5-pyranoside 
• 220172-60-1 (1R,2R,3R)-3-Benzyloxy-1-((4R,5R,4'R)-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-3-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-propane-1,2-diol 
• 220172-76-9 (2R,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-((1R,2R,3S,4S,5R,6R)-1,2,3,4,5,6,7-heptakis-benzyloxy-heptyl)-6-methoxy-tetrahydro-pyran 
• 1054655-44-5 methyl 2,3,4,6,7,8-hexa-O-benzyl-9,10:11,12-di-O-isopropylidene-α-L-erythro-L-manno-D-gluco-1,5-pyranoside 
• 220172-74-7 (2R,3R,4S,5S,6R,7R)-5,6,7-Tris-benzyloxy-7-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-heptane-1,2,3,4-tetraol 
• 220172-94-1 (1R,2R,3R)-3-Benzyloxy-1-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-3-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-propane-1,2-diol 
• 220172-91-8 (3aR,5R,5aS,8aS,8bR)-5-[(E)-(R)-3-Benzyloxy-3-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-propenyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 220172-59-8 (4S,5R,4'R)-5-[(E)-(R)-3-Benzyloxy-3-((2R,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-propenyl]-2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl] 
• 220172-62-3 (E)-3-((3aR,5R,5aS,8aS,8bR)-2,2,7,7-Tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran-5-yl)-1-((2S,3S,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-propenone 

Relevant academic research and scientific papers

The synthesis of glucosinolates deuterium labelled in the glucose fragment

A facile synthesis is described for 2,3,4,6-tetra-O-acetyl-thio-β-D- [1-2H,6-2H2]glucopyranose, which has been used to make an isotopically labelled desulphoglucosinolate, [1′- 2H,6′-2H2]de

A one-step C-linked disaccharide synthesis from carbohydrate allylsilanes and tri-O-acetyl-D-glucal

The reaction of protected glucuronic esters 2 and 7, as well as D-glucuronolactone derivative 11, with (trimethylsilyl)methylmagnesium chloride in ether led to the corresponding stable bis-silyl adducts 3, 8, and 12, respectively. In Peterson-type reactio

Stereoselective glycosidations of uronic acids

Stereoselective glycosidation and disaccharide formation of uronic acids were performed with silver perchlorate in acetonitrile. The course of the reaction is controlled by intermediate nitrilium acetonitrile conjugates, which are generated in situ.