1387007-03-5Relevant articles and documents
A pineno-salen type catalyst for the enantioselective Nozaki-Hiyama-Kishi reaction
Dhondge, Attrimuni P.,Shaikh, Ajam C.,Chen, Chinpiao
, p. 723 - 733 (2012/08/29)
A new class of pineno-salen type ligands 10, 11, 17, 20, 23, and 24 has been developed. The catalyst formed from chromium(II)-10 promotes the enantioselective Nozaki-Hiyama-Kishi allylation of alkyl and aryl aldehydes using allyl bromide. Notably, the asymmetric addition of vinyl halide to benzaldehyde was achieved with 24% ee.