328242-17-7

Basic information

• Product Name: (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene
• Synonyms: (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene
• CAS NO: 328242-17-7
• Molecular Weight: 279.382
• Mol File: 328242-17-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene(328242-17-7)
• EPA Substance Registry System: (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene(328242-17-7)

Safety Data

• Hazardous Substances Data: 328242-17-7(Hazardous Substances Data)

Upstream product

• 19890-00-7 (1S)-pinocarvone 
• 579-74-8 2-Methoxyacetophenone 
• 118-93-4 o-hydroxyacetophenone 
• 7785-26-4 (-)-α-pinene 

Downstream Products

• 328242-18-8 (1S,8R,9S)-8-isopropyl-5-(2-methoxy-phenyl)-10,10-dimethyl-6-aza-tricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene 
• 328242-19-9 2-((1S,8R,9S)-8-isopropyl-10,10-dimethyl-6-aza-tricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-trien-5-yl)-phenol 
• 561280-09-9 (1S,8R,9S)-5-(2-methoxy-phenyl)-8,10,10-trimethyl-6-aza-tricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene 
• 1387007-02-4 C₂₀H₂₁NO₃ 
• 1387007-03-5 C₁₈H₂₀N₂O 
• 561280-14-6 C₂₀H₂₃NO₂ 
• 328242-20-2 (5S,7S)-(+)-5,6,7,8-tetrahydro-6,6-dimethyl-2-(2-hydroxyphenyl)-5,7-methanoquinoline 

Relevant articles and documents

Mechanistic dichotomy in the asymmetric allylation of aldehydes with allyltrichlorosilanes catalyzed by chiral pyridine N-oxides

Detailed kinetic and computational investigation of the enantio- and diastereoselective allylation of aldehydes 1 with allyltrichlorosilanes 5, employing the pyridine N-oxides METHOX (9) and QUINOX (10) as chiral organocatalysts, indicate that the reaction can proceed through a dissociative (cationic) or associative (neutral) mechanism: METHOX apparently favors a pentacoordinate cationic transition state, while the less sterically demanding QUINOX is likely to operate via a hexacoordinate neutral complex. In both pathways, only one molecule of the catalyst is involved in the rate- and selectivity-determining step, which is supported by both experimental and computational data. Copyright

A pineno-salen type catalyst for the enantioselective Nozaki-Hiyama-Kishi reaction

A new class of pineno-salen type ligands 10, 11, 17, 20, 23, and 24 has been developed. The catalyst formed from chromium(II)-10 promotes the enantioselective Nozaki-Hiyama-Kishi allylation of alkyl and aryl aldehydes using allyl bromide. Notably, the asymmetric addition of vinyl halide to benzaldehyde was achieved with 24% ee.