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138715-28-3

2-Oxazolidineselone, 4-methyl-5-phenyl-, (4S,5R)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 138715-28-3 Structure

  • Basic information

    1. Product Name: 2-Oxazolidineselone, 4-methyl-5-phenyl-, (4S,5R)-
    2. Synonyms:
    3. CAS NO:138715-28-3
    4. Molecular Formula: C10H11NOSe
    5. Molecular Weight: 240.163
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 138715-28-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-Oxazolidineselone, 4-methyl-5-phenyl-, (4S,5R)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-Oxazolidineselone, 4-methyl-5-phenyl-, (4S,5R)-(138715-28-3)
    11. EPA Substance Registry System: 2-Oxazolidineselone, 4-methyl-5-phenyl-, (4S,5R)-(138715-28-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 138715-28-3(Hazardous Substances Data)

138715-28-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 138715-28-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,8,7,1 and 5 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 138715-28:
(8*1)+(7*3)+(6*8)+(5*7)+(4*1)+(3*5)+(2*2)+(1*8)=143
143 % 10 = 3
So 138715-28-3 is a valid CAS Registry Number.

138715-28-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone

1.2 Other means of identification

Product number -
Other names (4S,5R)-4-methyl-5-phenyloxazolidin-2-selone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:138715-28-3 SDS

138715-28-3Relevant articles and documents

Synthesis and Characterization of Chiral Oxazolidine-2-selones: A General One-Step Procedure from Readily Available Oxazolines

Peng, Jie,Barr, Mary E.,Ashburn, David A.,Odom, Jerome D.,Dunlap, R. Bruce,Silks, Louis A.

, p. 4977 - 4987 (2007/10/02)

The synthesis of a wide variety of chiral oxazolidine-2-selones from readily available 2-oxazolines has been accomplished in one step with yields ranging from 82 to 98percent.A mechanistic investigation of the formation of these selones has indicated the presence of intermediate anions which have been characterized by 13C and 77Se NMR spectroscopy.X-ray crystallographic data suggest the chiral selones exists as dimeric pairs or networks linked by unusual selenium hydrogen bonds.These chiral reagents exhibit extraordinary 77Se chemical shift sensitivity and are useful for the detection and quantitation of chirality at remotely disposed chiral centers.

Synthesis of (4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone: A Chiral Auxiliary Reagent Capable of Detecting the Enantiomers of (R,S)-Lipoic Acid by 77Se Nuclear Magnetic Resonance Spectroscopy

Silks, Louis A.,Peng, Jie,Odom, Jerome D.,Dunlap, R. Bruce

, p. 2495 - 2498 (2007/10/02)

(4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone was constructed in 5 steps on the 10-gram scale. 77Se NMR spectroscopic studies revealed that this selone served as a remarkably sensitive chiral auxiliary agent which readily distinguished the selone-coup

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