138715-29-4Relevant academic research and scientific papers
Synthesis and Characterization of Acylated Chiral Oxazolidine-2-selones: Selone Chiral Derivatizing Agents for the Detection and Quantitation of Remotely Disposed Chiral Centers
Peng, Jie,Barr, Mary E.,Ashburn, David A.,Lebioda, Lukasz,Garber, Albert R.,et al.
, p. 5540 - 5549 (2007/10/03)
Racemic and chiral carboxylic acids and acid chlorides are coupled cleanly to oxazolidine-2-selone chiral derivatizing agents (CDA's) with yields ranging from 85 to 99percent. 77Se NMR spectroscopy provides a highly sensitive method for the determination
Synthesis of (4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone: A Chiral Auxiliary Reagent Capable of Detecting the Enantiomers of (R,S)-Lipoic Acid by 77Se Nuclear Magnetic Resonance Spectroscopy
Silks, Louis A.,Peng, Jie,Odom, Jerome D.,Dunlap, R. Bruce
, p. 2495 - 2498 (2007/10/02)
(4S,5R)-(-)-4-Methyl-5-phenyloxazolidine-2-selone was constructed in 5 steps on the 10-gram scale. 77Se NMR spectroscopic studies revealed that this selone served as a remarkably sensitive chiral auxiliary agent which readily distinguished the selone-coup
